Selected Publications

2023

Large 31P-NMR enhancements in liquid state dynamic nuclear polarization through radical/target molecule non-covalent interactionM. Reinhard, M. Levien, M. Bennati, T. OrlandoPhysical Chemistry Chemical Physics 25, 822-828.

2022

Theoretical analysis of scalar relaxation in 13C-DNP in liquidsT. Orlando, I. Kuprov, M. HillerJournal of Magnetic Resonance Open 10-11, 100040.

2021

Spin density localization and accessibility in organic radicals for liquid-state DNP efficiencyM. Levien, M. Reinhard, M. Hiller, I. Tkach, M. Bennati, T. OrlandoPhysical Chemistry Chemical Physics 23, 4480–4485.

2020

Nitroxide derivatives for dynamic nuclear polarization in liquids: the role of rotational diffusionM. Levien, M. Hiller, I. Tkach, M. Bennati, T. OrlandoThe Journal of Physical Chemistry Letters 11, 1629-1635
Low temperature anomalies in Muon Spin Relaxation of full and hollow γ-Fe2O3 nanoparticles: a pathway to detect unusual local spin dynamicsM. Basini, S. Sanna, T. Orlando, L. Bordonali, M. Cobianchi, P. Arosio, M. Mariani, D. Peddis, V. Bonanni, R. Mathieu, T. Kalaivani, G. Singh, J. Larionova, Y. Guari, L. Lartigue, A. LascialfariPhysical Review B 102, 195424 

2019

Dynamic nuclear polarization of 13C nuclei in the liquid state over a 10 Tesla field rangeT. Orlando, R. Dervişoğlu, M. Levien, I. Tkach, T.F. Prisner, L.B. Andreas, V.P. Denysenkov, M. BennatiAngewandte Chemie 58, 1402–1406
Role of Zn2+ Substitution on the Magnetic, Hyperthermic, and Relaxometric Properties of Cobalt Ferrite NanoparticlesM. Albino, E. Fantechi, C. Innocenti, A. López-Ortega, V. Bonanni, G. Campo, F. Pineider, M. Gurioli, P. Arosio, T. Orlando, G. Bertoni, C. De Julián Fernández, A. Lascialfari, C. SangregorioThe Journal of Physical Chemistry C 123, 6148–6157

Book chapter

Overhauser DNP in liquids on 13C nucleiM. Bennati, T. OrlandoeMagRes 8, 11–18
inHandbook of High Field Dynamic Nuclear Polarizationed.: V. K. Michaelis, R. G. Griffin, B. Corzilius, S. VegaWiley, 2020

2018

Spin dynamics in the single-ion magnet [Er(W5O18)2]9−M. Mariani, F. Borsa, M.J. Graf, S. Sanna, M. Filibian, T. Orlando, S.K.P. Velu, E. Coronado, A. LascialfariPhysical Review B 97, 144414

2019

Local spin dynamics of iron oxide magnetic nanoparticles dispersed in different solvents with variable size and shape: A 1H NMR studyM. Basini, T. Orlando, P. Arosio, M.F. Casula, D. Espa, S. Murgia, C. Sangregorio, C. Innocenti, A. LascialfariThe Journal of Chemical Physics 146, 034703

2016

NMR relaxation induced by iron oxide particles: testing theoretical modelsY. Gossuin, T. Orlando, M. Basini, D. Henrard, A. Lascialfari, C. Mattea, S. Stapf, Q.L. VuongNanotechnology 27, 155706
On the magnetic anisotropy and nuclear relaxivity effects of Co and Ni doping in iron oxide nanoparticlesT. Orlando, M. Albino, F. Orsini, C. Innocenti, M. Basini, P. Arosio, C. Sangregorio, M. Corti, A. LascialfariJournal of Applied Physics 119, 134301
Persistence of slow dynamics in Tb(OETAP)2 single molecule magnets embedded in conducting polymersT. Orlando, M. Filibian, S. Sanna, N. Giménez-Agullo, C.S. de Pipaón, P. Ballester, J.R. Galán-Mascarós, P. CarrettaJournal of Physics: Condensed Matter 28, 386002
Characterization of magnetic nanoparticles from Magnetospirillum Gryphiswaldense as potential theranostics toolsT. Orlando, S. Mannucci, E. Fantechi, G. Conti, S. Tambalo, A. Busato, C. Innocenti, L. Ghin, R. Bassi, P. Arosio, F. Orsini, C. Sangregorio, M. Corti, M.F. Casula, P. Marzola, A. Lascialfari, A. SbarbatiContrast Media & Molecular Imaging 11, 139–145

2015

Spin dynamics in hybrid iron oxide−gold nanostructuresT. Orlando, A. Capozzi, E. Umut, L. Bordonali, M. Mariani, P. Galinetto, F. Pineider, C. Innocenti, P. Masala, F. Tabak, M. Scavini, P. Santini, M. Corti, P. Ghigna, A. LascialfariThe Journal of Physical Chemistry C 119, 1224–1233

2014

Lascialfari, NMR as evaluation strategy for cellular uptake of nanoparticlesT. Orlando, A. Paolini, F. Pineider, E. Clementi, F. Pasi, Y. Guari, J. Larionova, L. Sacchi, R. Nano, M. Corti, A. LascialfariNano Letters 14, 3959–3965

2013

Hybrid iron oxide-copolymer micelles and vesicles as contrast agents for MRI: impact of the nanostructure on the relaxometric propertiesP. Arosio, J. Thévenot, T. Orlando, F. Orsini, M. Corti, M. Mariani, L. Bordonali, C. Innocenti, C. Sangregorio, H. Oliveira, S. Lecommandoux, A. Lascialfari, O. SandreJournal of Material Chemistry B 1, 5317–5328